Addition of Ethylene or Hydrogen to a Main-Group Metal Cluster under Mild Conditions
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منابع مشابه
Addition of ethylene or hydrogen to a main-group metal cluster under mild conditions.
Reaction of the tin cluster Sn8(Ar(Me6))4(Ar(Me6)=C6H2-2,6-(C6H3-2,4,6-Me3)2) with excess ethylene or dihydrogen at 25 °C/1 atmosphere yielded two new clusters that incorporated ethylene or hydrogen. The reaction with ethylene yielded Sn4(Ar(Me6))4(C2H2)5 that contained five ethylene moieties bridging four aryl substituted tin atoms and one tin-tin bond. Reaction with H2 produced a cyclic tin s...
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We have studied the hydrogen sorption on three well-known organic hosts that possess vacant lattice voids large enough to accommodate H2 molecules.
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Recently, we have predicted [Phys. Rev. Lett. 97, 226102 (2006)] that a single ethylene molecule can form stable complexes with light transition metals (TMs) such as Ti and the resulting TMn-ethylene complex can absorb up to ~ 12 and 14 wt % hydrogen for n=1 and 2, respectively. Here we extend this study to include a large number of other metals and different isomeric structures. We obtained in...
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The CH-activation of THF is realized in a zinc-mediated process using a dibromocyclopropane as a crucial additive. The highly regioselective addition to aryl-substituted propiolates as well as the regio- and stereoselective addition to diynes are described.
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2015
ISSN: 1433-7851
DOI: 10.1002/anie.201411595